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A serious train wreck occurred in Danville on September 27, 1903. "Old 97", the Southern Railway's crack express mail train, was running behind schedule. Its engineer "gave her full throttle", but the speed of the train caused it to jump the tracks while on a high trestle crossing the valley of the Dan River. The engine and five cars plunged into the ravine below, killing nine and injuring seven. The locomotive and its engineer, Joseph A. ("Steve") Broadey, were memorialized in song. A historic marker at the train crash site is located on U.S. 58 between Locust Lane and North Main Street. A mural of the Wreck of the Old 97 has been painted on a downtown Danville building to commemorate the incident.

Low-bandgap near-infrared polymers are usually synthesized using the common donor-acceptor (D-A) approach. However, recently polymer chemists are introducing more complex chemical concepts for better fine tuning of their optoelectronic properties. Usually these studies are limited to one or two polymer examples in each case study so far, though. In this study, the dependence of optoelectronic and macroscopic (device performance) properties in a series of six new D-A 1 -D-A 2 low bandgap semiconducting polymers is reported for the first time. Correlation between the chemical structure of single-component polymer films and their optoelectronic properties has been achieved in terms of absorption maxima, optical bandgap, ionization potential, and electron affinity. Preliminary organic photovoltaic results based on blends of the D-A 1 -D-A 2 polymers as the electron donor mixed with the fullerene derivative [6,6]-phenyl-C 71 -butyric acid methyl ester demonstrate power conversion efficiencies close to 4% with short-circuit current densities (J sc ) of around 11 mA cm -2 , high fill factors up to 0.70, and high open-circuit voltages (V oc s) of 0.70 V. All the devices are fabricated in an inverted architecture with the photoactive layer processed in air with doctor blade technique, showing the compatibility with roll-to-roll large-scale manufacturing processes. 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. 350c69d7ab

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